1992 Summer Olympics |
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| Extra-Lightweight, Men | Antoni Molné | =23 | |
1996 Summer Olympics |
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| Half-Lightweight, Men | Antoni Molné | =21 | |
2004 Summer Olympics |
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| Middleweight, Men | Toni Besolí | AC | |
2008 Summer Olympics |
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| Half-Lightweight, Men | Daniel García | =13 | |
2010 Summer Youth Olympics |
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| ≤66 kilograms, Boys | Patrik Ferreira Martins | =9 | |
2012 Summer Olympics |
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| Half-Lightweight, Men | Daniel García | =9 | |
2016 Summer Olympics |
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| Half-Middleweight, Women | Laura Sallés | =17 |