1984 Summer Olympics |
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| Half-Lightweight, Men | Bienvenu Mbida | =14 | |
| Half-Middleweight, Men | Christophe Wogo | =20 | |
| Middleweight, Men | Séraphin Okuaka | =18 | |
1996 Summer Olympics |
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| Middleweight, Men | Abel Ndenguet | =21 | |
2000 Summer Olympics |
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| Half-Lightweight, Men | Kevin Ngapoula-Mbembo | AC | |
2004 Summer Olympics |
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| Heavyweight, Women | Tatiana Bvegadzi | AC | |
2016 Summer Olympics |
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| Heavyweight, Men | Deo Gracia Ngokaba | =17 |