1980 Summer Olympics |
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| Bantamweight, Men | José Luís de Almeida | =17 | |
| Featherweight, Men | Abílio Cabral | =17 | |
| Lightweight, Men | Alberto Coelho | =17 | |
1988 Summer Olympics |
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| Bantamweight, Men | Manuel Gomes | =33 | |
| Welterweight, Men | Adão N'Zuzi | =33 | |
| Light-Middleweight, Men | Apolinário de Silveira | =9 | |
1992 Summer Olympics |
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| Welterweight, Men | Francisco Moniz | =17 | |
2012 Summer Olympics |
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| Heavyweight, Men | Tumba Silva | DNS |