1984 Summer Olympics |
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| Lightweight, Men | Dieudonné Kossi | =17 | |
| Welterweight, Men | Antoine Longoudé | =32 | |
1988 Summer Olympics |
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| Welterweight, Men | Fidèle Mohinga | =17 | |
| Light-Middleweight, Men | Moussa Wiawindi | =32 | |
2008 Summer Olympics |
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| Welterweight, Men | Bruno Bongongo | =17 | |
2016 Summer Olympics |
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| Flyweight, Women | Judith Mbougnade | =9 |