2008 Summer Olympics |
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| 10 kilometres Open Water, Men | Kiko Hervás | 13 | |
| 10 kilometres Open Water, Women | Yurema Requena | 13 | |
2012 Summer Olympics |
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| 10 kilometres Open Water, Men | Kiko Hervás | 23 | |
| 10 kilometres Open Water, Women | Erika Villaécija | 7 | |
2016 Summer Olympics |
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| 10 kilometres Open Water, Women | Erika Villaécija | 17 | |
2020 Summer Olympics |
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| 10 kilometres Open Water, Men | Alberto Martínez | 18 | |
| 10 kilometres Open Water, Women | Paula Ruiz | 16 | |
2024 Summer Olympics |
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| 10 kilometres Open Water, Men | Carlos Garach | DNF | |
| 10 kilometres Open Water, Women | Ángela Martínez | 10 | |
| María de Valdés | 17 |
