| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2000 Summer Olympics | Santiago López-Vázquez / Javier de la Plaza | 4 | |
| 2004 Summer Olympics | Iker Martínez / Xabier Fernández | 1 | Gold |
| 2008 Summer Olympics | Iker Martínez / Xabier Fernández | 2 | Silver |
| 2012 Summer Olympics | Xabier Fernández / Iker Martínez | 12 | |
| 2016 Summer Olympics | Diego Botín / Iago López | 9 | |
| 2020 Summer Olympics | Diego Botín / Iago López | 4 | |
| 2024 Summer Olympics | Diego Botín / Florián Trittel | 1 | Gold |
