| Date | 11 August 2016 — 11:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 10 | Roberto Bautista |  ESP | 2 | 6 | 7 | |
| – | Gilles Müller |  LUX | 0 | 4 | 6 |
| Roberto Bautista | Gilles Müller | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 4 |
| Set 2 | 7 | 6 |
| Tie-break 2 | 7 | 4 |
