| Date | 8 August 2016 — 16:39 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Gianluca Moscarella |  ITA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 6 | Gaël Monfils |  FRA | 2 | 6 | 6 | |
| – | Rogério Dutra |  BRA | 0 | 2 | 4 |
| Gaël Monfils | Rogério Dutra | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 2 |
| Set #2 | 6 | 4 |
