| Date | 7 August 2016 — 19:32 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| – | Juan Sebastián Cabal / Robert Farah |  COL | 2 | 7 (7) | 6 | |
| 1 | Pierre-Hugues Herbert / Nicolas Mahut |  FRA | 0 | 6 (4) | 3 |
Juan Sebastián Cabal / Robert Farah| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Juan Sebastián Cabal | ||||
| – | Robert Farah | ||||
| Team Totals | |||||
Pierre-Hugues Herbert / Nicolas Mahut| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Pierre-Hugues Herbert | ||||
| – | Nicolas Mahut | ||||
| Team Totals | |||||
