| Date | 9 August 2016 — 18:15 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Paula Vieira |  BRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 4 | Garbiñe Muguruza / Carla Suárez |  ESP | 2 | 7 | 2 | 6 | |
| – | Kirsten Flipkens / Yanina Wickmayer |  BEL | 1 | 5 | 6 | 2 |
Garbiñe Muguruza / Carla Suárez| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Garbiñe Muguruza | ||||
| – | Carla Suárez | ||||
| Team Totals | |||||
Kirsten Flipkens / Yanina Wickmayer| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Kirsten Flipkens | ||||
| – | Yanina Wickmayer | ||||
| Team Totals | |||||
