| Date | 6 August 2016 — 20:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 5 | Timea Bacsinszky / Martina Hingis |  SUI | 2 | 2 | 6 | 4 | 6 | |
| – | Daria Gavrilova / Samantha Stosur |  AUS | 1 | 1 | 4 | 6 | 2 |
Timea Bacsinszky / Martina Hingis| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Timea Bacsinszky | ||||
| – | Martina Hingis | ||||
| Team Totals | |||||
Daria Gavrilova / Samantha Stosur| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Daria Gavrilova | ||||
| – | Samantha Stosur | ||||
| Team Totals | |||||
