| Date | 7 August 2016 — 18:49 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 5) | |
| Chair Umpire | Jaume Campistol |  ESP |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 6 | Andrea Hlaváčková / Lucie Hradecká |  CZE | 2 | 7 (7) | 1 | 6 | |
| – | Olha Savchuk / Elina Svitolina |  UKR | 1 | 6 (1) | 6 | 4 |
Andrea Hlaváčková / Lucie Hradecká| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Andrea Hlaváčková | ||||
| – | Lucie Hradecká | ||||
| Team Totals | |||||
Olha Savchuk / Elina Svitolina| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Olha Savchuk | ||||
| – | Elina Svitolina | ||||
| Team Totals | |||||
