| Date | 11 August 2016 — 16:29 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Marija Čičak |  CRO |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| – | Teliana Pereira / Marcelo Melo |  BRA | 2 | 7 | 7 | |
| 1 | Caroline Garcia / Nicolas Mahut |  FRA | 0 | 6 | 6 |
Teliana Pereira / Marcelo Melo| Pos | Seed | Competitor | Tie-break 1 | Tie-break 2 | |||
|---|---|---|---|---|---|---|---|
| – | Teliana Pereira | – | – | ||||
| – | Marcelo Melo | – | – | ||||
| Team Totals | 7 | 7 | |||||
Caroline Garcia / Nicolas Mahut| Pos | Seed | Competitor | Tie-break 1 | Tie-break 2 | |||
|---|---|---|---|---|---|---|---|
| – | Caroline Garcia | – | – | ||||
| – | Nicolas Mahut | – | – | ||||
| Team Totals | 4 | 1 | |||||
