1992 Summer Olympics |
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| Extra-Lightweight, Men | Nonilobal Hien | =35 | |
2000 Summer Olympics |
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| Half-Middleweight, Men | Salifou Koucka Ouiminga | AC | |
2004 Summer Olympics |
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| Extra-Lightweight, Women | Konkiswinde Hanatou Ouelogo | AC | |
2008 Summer Olympics |
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| Extra-Lightweight, Women | Konkiswinde Hanatou Ouelogo | =15 | |
2012 Summer Olympics |
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| Half-Middleweight, Women | Séverine Nébié | =9 | |
2016 Summer Olympics |
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| Heavyweight, Men | Rachid Sidibé | =17 | |
2020 Summer Olympics |
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| Lightweight, Men | Lucas Diallo | =17 |