| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1996 Summer Olympics | Sun Man / Liu Jianjun | 3 | Bronze |
| Peng Xingyong / Chen Xingdong | 4 | ||
| Wang Xiaoyuan / Tao Xiaoqiang | =5 | ||
| 2000 Summer Olympics | Gao Ling / Zhang Jun | 1 | Gold |
| Chen Lin / Chen Qiqiu | =9 | ||
| Ge Fei / Liu Yong | =9 | ||
| 2004 Summer Olympics | Zhang Jun / Gao Ling | 1 | Gold |
| Chen Qiqiu / Zhao Tingting | =5 | ||
| 2008 Summer Olympics | He Hanbin / Yu Yang | 3 | Bronze |
| Gao Ling / Zheng Bo | =9 | ||
| 2012 Summer Olympics | Zhang Nan / Zhao Yunlei | 1 | Gold |
| Xu Chen / Ma Jin | 2 | Silver | |
| 2016 Summer Olympics | Zhang Nan / Zhao Yunlei | 3 | Bronze |
| Xu Chen / Ma Jin | 4 | ||
| 2020 Summer Olympics | Wang Yilyu / Huang Dongping | 1 | Gold |
| Zheng Siwei / Huang Yaqiong | 2 | Silver | |
| 2024 Summer Olympics | Zheng Siwei / Huang Yaqiong | 1 | Gold |
| Feng Yanzhe / Huang Dongping | =5 |