| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1996 Summer Olympics | Laura Blanco | 20 | |
| Silvia Rovira | 26 | ||
| 2000 Summer Olympics | Marga Fullana | 3 | Bronze |
| Silvia Rovira | 14 | ||
| 2004 Summer Olympics | Marga Fullana | DNF | |
| 2008 Summer Olympics | Marga Fullana | DNF | |
| 2020 Summer Olympics | Rocío García | 26 |
