| Date | 9 August 2016 — 15:33 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Jake Garner |  USA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Fabio Fognini |  ITA | 2 | 2 | 4 | 6 | 7 | |
| 16 | Benoît Paire |  FRA | 1 | 1 | 6 | 4 | 6 |
| Fabio Fognini | Benoît Paire | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 4 | 6 |
| Set 2 | 6 | 4 |
| Set 3 | 7 | 6 |
| Tie-break 3 | 7 | 5 |
