| Date | 6 August 2016 — 22:26 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | John Blom |  AUS |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 6 | Gaël Monfils |  FRA | 2 | 2 | 6 | 6 | |
| – | Vasek Pospisil |  CAN | 0 | 0 | 1 | 3 |
| Gaël Monfils | Vasek Pospisil | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 1 |
| Set 2 | 6 | 3 |
