| Date | 19 September 2000 | |
|---|---|---|
| Location | New South Wales Tennis Centre, Olympic Park, Sydney, New South Wales (Court #3) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Nicolás Massú |  CHI | 2 | 2 | 6 | 7 | |
| – | Slava Doseděl |  CZE | 0 | 0 | 2 | 6 |
| Nicolás Massú | Slava Doseděl | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 2 |
| Set 2 | 7 | 6 |
| Tie-break 2 | 7 | 5 |
