1992 Summer Olympics |
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| Bantamweight, Men | Diego Yáñez | =5 | |
| Lightweight, Men | Humberto Norambuena | =5 | |
2000 Summer Olympics |
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| Welterweight, Men | Felipe Soto | =7 | |
2012 Summer Olympics |
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| Featherweight, Women | Yeny Contreras | =11 | |
2014 Summer Youth Olympics |
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| ≤55 kilograms, Boys | Gerard Arriagada | DQ | |
2016 Summer Olympics |
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| Featherweight, Men | Ignacio Morales | =11 | |
2024 Summer Olympics |
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| Welterweight, Men | Joaquín Churchill | =11 | |
| Heavyweight, Women | Fernanda Aguirre | =11 |
