| Date | 9 August 2016 — 12:46 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Carlos Ramos |  POR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 2 | Andy Murray |  GBR | 2 | 2 | 6 | 6 | |
| – | Juan Mónaco |  ARG | 0 | 0 | 3 | 1 |
| Andy Murray | Juan Mónaco | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 1 |
