| Date | 6 August 2016 — 14:40 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 6) | |
| Chair Umpire | Marijana Veljović |  SRB |
| Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| Gastão Elias |  POR | 2 | 2 | 7 | 7 | |
| Thanasi Kokkinakis |  AUS | 0 | 0 | 6 | 6 |
| Gastão Elias | Thanasi Kokkinakis | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 7 | 6 |
| Set 2 | 7 | 6 |
| Tie-break 1 | 7 | 4 |
| Tie-break 2 | 7 | 3 |
