| Date | 9 August 2016 — 20:31 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Marija Čičak |  CRO |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 7 | Daniel Nestor / Vasek Pospisil |  CAN | 2 | 6 | 6 | |
| – | Fabio Fognini / Andreas Seppi |  ITA | 0 | 3 | 1 |
Daniel Nestor / Vasek Pospisil| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Daniel Nestor | ||||
| – | Vasek Pospisil | ||||
| Team Totals | |||||
Fabio Fognini / Andreas Seppi| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Fabio Fognini | ||||
| – | Andreas Seppi | ||||
| Team Totals | |||||
