| Date | 6 August 2016 — 11:11 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 9) | |
| Chair Umpire | Pascal Maria |  FRA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 5 | Florin Mergea / Horia Tecău |  ROU | 2 | 6 | 6 | |
| – | Federico Delbonis / Guillermo Durán |  ARG | 0 | 3 | 2 |
Florin Mergea / Horia Tecău| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Florin Mergea | ||||
| – | Horia Tecău | ||||
| Team Totals | |||||
Federico Delbonis / Guillermo Durán| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Federico Delbonis | ||||
| – | Guillermo Durán | ||||
| Team Totals | |||||
