| Date | 13 August 2016 — 12:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Paula Vieira |  BRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 11 | Petra Kvitová |  CZE | 2 | 7 | 2 | 6 | |
| 7 | Madison Keys |  USA | 1 | 5 | 6 | 2 |
| Petra Kvitová | Madison Keys | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 7 | 5 |
| Set #2 | 2 | 6 |
| Set #3 | 6 | 2 |
