| Date | 11 August 2016 — 13:39 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Tamara Vrhovec-Wójcik |  CRO |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 11 | Petra Kvitová |  CZE | 2 | 6 | 6 | |
| 15 | Elina Svitolina |  UKR | 0 | 2 | 0 |
| Petra Kvitová | Elina Svitolina | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 2 |
| Set #2 | 6 | 0 |
