| Date | 9 August 2016 — 17:26 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Ali Nili |  USA |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 2 | Angelique Kerber |  GER | 2 | 6 | 7 | |
| 13 | Samantha Stosur |  AUS | 0 | 0 | 5 |
| Angelique Kerber | Samantha Stosur | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 0 |
| Set 2 | 7 | 5 |
