| Date | 8 August 2016 — 18:50 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Julie Kjendlie |  NOR |
| Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|
| Serena Williams |  USA | 2 | 7 (7) | 6 | |
| Alizé Cornet |  FRA | 0 | 6 (5) | 2 |
| Serena Williams | Alizé Cornet | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 7 (7) | 6 (5) |
| Set 2 | 6 | 2 |
