| Date | 7 August 2016 — 17:48 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 7) | |
| Chair Umpire | Félix Torralba |  ESP |
| Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|
| Laura Siegemund |  GER | 2 | 1 | 6 | 6 | |
| Tsvetana Pironkova |  BUL | 1 | 6 | 4 | 2 |
| Laura Siegemund | Tsvetana Pironkova | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 1 | 6 |
| Set #2 | 6 | 4 |
| Set #3 | 6 | 2 |
