| Date | 6 August 2016 — 11:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Paula Vieira |  BRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 7 | Madison Keys |  USA | 2 | 2 | 6 | 6 | |
| – | Danka Kovinić |  MNE | 0 | 0 | 3 | 3 |
| Madison Keys | Danka Kovinić | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 3 |
