| Date | 6 August 2016 — 11:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Miriam Bley |  GER |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Sara Errani |  ITA | 2 | 2 | 4 | 6 | 6 | |
| – | Kiki Bertens |  NED | 1 | 1 | 6 | 4 | 3 |
| Sara Errani | Kiki Bertens | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 4 | 6 |
| Set 2 | 6 | 4 |
| Set 3 | 6 | 3 |
