| Date | 6 August 2016 — 19:41 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Alison Hughes |  GBR |
| Seed | Competitor | NOC | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|
| 4 | Garbiñe Muguruza / Carla Suárez |  ESP | 2 | 7 (8) | 6 | |
| – | Paula Gonçalves / Teliana Pereira |  BRA | 0 | 6 (6) | 2 |
Garbiñe Muguruza / Carla Suárez| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Garbiñe Muguruza | ||||
| – | Carla Suárez | ||||
| Team Totals | |||||
Paula Gonçalves / Teliana Pereira| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Paula Gonçalves | ||||
| – | Teliana Pereira | ||||
| Team Totals | |||||
