| Date | 19 August 2004 — 10:20 |
|---|---|
| Location | Olympiako Kentro Ugrou Stivou, Olympiako Athletiko Kentro Athinon Spiros Loues, Athina (Main Pool) |
| Pos | Lane | Competitor | NOC | Time | Reaction Time | |||
|---|---|---|---|---|---|---|---|---|
| 1 | 4 | Gary Hall, Jr. |  USA | 22.04 | 0.72 | |||
| 2 | 8 | Salim Iles |  ALG | 22.26 | 0.66 | |||
| =3 | 5 | Oleksandr Volynets |  UKR | 22.41 | 0.84 | |||
| =3 | 2 | Roland Schoeman |  RSA | 22.41 | 0.63 | |||
| 5 | 1 | Stefan Nystrand |  SWE | 22.42 | 0.70 | |||
| 6 | 6 | Lyndon Ferns | RSA | 22.53 | 0.72 | |||
| 7 | 3 | Pieter van den Hoogenband |  NED | 22.56 | 0.74 | |||
| 8 | 7 | Ashley Callus |  AUS | 22.82 | 0.69 |
