1992 Summer Olympics |
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| Half-Heavyweight, Men | Joseph Ndjumbi | =21 | |
| Half-Heavyweight, Women | Mélanie Engoang | =16 | |
1996 Summer Olympics |
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| Middleweight, Women | Mélanie Engoang | =9 | |
2000 Summer Olympics |
|||
| Heavyweight, Men | Steeve Nguema Ndong | =13 | |
| Half-Heavyweight, Women | Mélanie Engoang | =20 | |
2004 Summer Olympics |
|||
| Half-Heavyweight, Women | Mélanie Engoang | =19 | |
2008 Summer Olympics |
|||
| Extra-Lightweight, Women | Sandrine Ilendou | =19 | |
2012 Summer Olympics |
|||
| Half-Heavyweight, Women | Audrey Koumba | =9 | |
2014 Summer Youth Olympics |
|||
| ≤52 kilograms, Girls | Sandrine Mbazoghe Endamne | =17 | |
2016 Summer Olympics |
|||
| Half-Middleweight, Men | Paul Kibikai | =9 | |
| Half-Heavyweight, Women | Sarah Mazouz | =9 | |
2018 Summer Youth Olympics |
|||
| ≤66 kilograms, Boys | Loreince Nanekoula | =13 | |
| ≤52 kilograms, Girls | Augusta Ambourouet | =13 | |
2020 Summer Olympics |
|||
| Half-Heavyweight, Women | Sarah Mazouz | =17 | |
2024 Summer Olympics |
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| Extra-Lightweight, Women | Virginia Aymard | =17 |
