| 1996 Summer Olympics |
São Tomé and Príncipe
|
Sortelina Pires |
Athletics |
|
|
| 2000 Summer Olympics |
São Tomé and Príncipe
|
Naide Gomes |
Athletics |
|
155 |
| 2004 Summer Olympics |
São Tomé and Príncipe
|
Fumilay da Fonseca |
Athletics |
|
163 |
| 2008 Summer Olympics |
São Tomé and Príncipe
|
Celma Bonfim |
Athletics |
|
67 |
| 2010 Summer Youth Olympics |
São Tomé and Príncipe
|
Vanderley Cabral de Assuncao Silva |
Canoe Sprint |
|
160 |
| 2012 Summer Olympics |
São Tomé and Príncipe
|
Lecabela Quaresma |
Athletics |
|
160 |
| 2014 Summer Youth Olympics |
São Tomé and Príncipe
|
Albenzinia Soares |
Athletics |
|
163 |
| 2016 Summer Olympics |
São Tomé and Príncipe
|
Buly Triste |
Canoe Sprint |
|
166 |
| 2018 Summer Youth Olympics |
São Tomé and Príncipe
|
Fabio Moniz |
Athletics |
|
166 |
| 2020 Summer Olympics |
São Tomé and Príncipe
|
Buly Triste |
Canoe Sprint |
|
74 |
| 2020 Summer Olympics |
São Tomé and Príncipe
|
D'jamila Tavares |
Athletics |
|
74 |
| 2024 Summer Olympics |
São Tomé and Príncipe
|
Gorete Semedo |
Athletics |
|
164 |
| 2024 Summer Olympics |
São Tomé and Príncipe
|
Roldeney de Oliveira |
Judo |
|
164 |