| Date | 8 August 2016 — 10:56 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Jake Garner |  USA |
| Seed | Competitor | NOC | Sets Won | Sets Won | |
|---|---|---|---|---|---|
| – | Andrej Martin |  SVK | – | walkover | |
| 13 | Philipp Kohlschreiber |  GER | – |
| Andrej Martin | Philipp Kohlschreiber | |
|---|---|---|
| Sets Won | – | – |
