| Date | 6 August 2016 — 13:12 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 6) | |
| Chair Umpire | Kader Nouni |  FRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 8 | Roberto Bautista / David Ferrer |  ESP | 2 | 2 | 6 | 6 | |
| – | Lukáš Rosol / Radek Štěpánek |  CZE | 0 | 0 | 1 | 4 |
Roberto Bautista / David Ferrer| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Roberto Bautista | ||||
| – | David Ferrer | ||||
| Team Totals | |||||
Lukáš Rosol / Radek Štěpánek| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Lukáš Rosol | ||||
| – | Radek Štěpánek | ||||
| Team Totals | |||||
