| Date | 9 August 2016 — 11:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Miriam Bley |  GER |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 11 | Petra Kvitová |  CZE | 2 | 2 | 4 | 6 | 6 | |
| – | Yekaterina Makarova |  RUS | 1 | 1 | 6 | 4 | 4 |
| Petra Kvitová | Yekaterina Makarova | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 4 | 6 |
| Set 2 | 6 | 4 |
| Set 3 | 6 | 4 |
