| Date | 21 September 2000 — 19:00 | |
|---|---|---|
| Location | New South Wales Tennis Centre, Olympic Park, Sydney, New South Wales (Centre Court) | |
| Chair Umpire | Hermione Hunter |  GBR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 2 | Venus Williams |  USA | 2 | 2 | 6 | 6 | |
| – | Tamarine Tanasugarn |  THA | 0 | 0 | 2 | 3 |
| Venus Williams | Tamarine Tanasugarn | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 2 |
| Set 2 | 6 | 3 |
