1988 Summer Olympics |
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| Lightweight, Men | Daniel Dohou Dossou | =19 | |
2012 Summer Olympics |
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| Extra-Lightweight, Men | Jacob Gnahoui | =33 | |
2016 Summer Olympics |
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| Middleweight, Men | Celtus Dossou Yovo | =9 | |
2020 Summer Olympics |
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| Middleweight, Men | Celtus Dossou Yovo | =17 | |
2024 Summer Olympics |
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| Half-Middleweight, Men | Valentin Houinato | =17 |
