Athletics |
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| 800 metres, Men | Ilunga Kafila | 8 h1 r1/3 | |
| 1,500 metres, Men | Kaleka Mutoke | 10 h4 r1/3 | |
| 5,000 metres, Men | Willy Kalombo | DNS | |
| Marathon, Men | Willy Kalombo | 50 | |
| 4 × 400 metres Relay, Men | Zaire | 8 h1 r1/2 | |
| Ilunga Kafila • Luasa Batungile • Kaleka Mutoke • Shintu Kibambe | |||
| 100 metres, Women | Muyegbe Mubala | 8 h5 r1/4 | |
| Marathon, Women | Christine Bakombo | 37 | |
| Long Jump, Women | Muyegbe Mubala | DNS | |
Boxing |
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| Middleweight, Men | Mohamed Siluvangi | =9 | |
Cycling Road |
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| Road Race, Individual, Men | Mobange Amisi | DNF | |
| Selenge Kimoto | DNF | ||
| Ndjibu N'Golomingi | DNF | ||
Judo |
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| Extra-Lightweight, Men | Bosolo Mobando | =23 | |
| Half-Lightweight, Men | Dikubenga Mavatiku | =17 | |
| Lightweight, Men | Lusambu Mafuta | =13 | |
| Half-Middleweight, Men | Musuyu Kutama | =34 | |
| Middleweight, Men | Ilualoma Isako | =17 | |
| Half-Heavyweight, Men | Mamute Mbonga | =21 | |