| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 2000 Summer Olympics | Cristina Vitali | =11 | |
| 2004 Summer Olympics | Chiara Càinero | 8 | |
| 2008 Summer Olympics | Chiara Càinero | 1 | Gold |
| 2012 Summer Olympics | Chiara Càinero | 5 | |
| 2016 Summer Olympics | Diana Bacosi | 1 | Gold |
| Chiara Càinero | 2 | Silver | |
| 2020 Summer Olympics | Diana Bacosi | 2 | Silver |
| Chiara Càinero | 20 | ||
| 2024 Summer Olympics | Diana Bacosi | 15 | |
| Martina Bartolomei | 16 |
