| Date | 7 August 2016 — 12:42 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 5) | |
| Chair Umpire | Alison Hughes |  GBR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 10 | Roberto Bautista |  ESP | 1 | 6 (4) | 6 | 0 | |
| – | Andrey Kuznetsov |  RUS | 1 | 7 (7) | 2 | 0 ret |
| Roberto Bautista | Andrey Kuznetsov | |
|---|---|---|
| Sets Won | 1 | 1 |
| Set #1 | 6 (4) | 7 (7) |
| Set #2 | 6 | 2 |
| Set #3 | 0 | 0 ret |
