| Date | 7 August 2016 — 14:30 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Jake Garner |  USA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 2 | Andy Murray |  GBR | 2 | 2 | 6 | 6 | |
| – | Viktor Troicki |  SRB | 0 | 0 | 3 | 2 |
| Andy Murray | Viktor Troicki | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 2 |
