| Date | 12 August 2016 — 19:14 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Alison Hughes |  GBR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| 6 | Marc López / Rafael Nadal |  ESP | 2 | 2 | 6 | 3 | 6 | |
| 5 | Florin Mergea / Horia Tecău |  ROU | 1 | 1 | 2 | 6 | 4 |
Marc López / Rafael Nadal| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Marc López | ||||
| – | Rafael Nadal | ||||
| Team Totals | |||||
Florin Mergea / Horia Tecău| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Florin Mergea | ||||
| – | Horia Tecău | ||||
| Team Totals | |||||
