| Date | 7 August 2016 — 20:24 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Mohamed El-Jennati |  MAR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Thomaz Bellucci / André Sá |  BRA | 2 | 7 (8) | 7 (16) | |
| 2 | Andy Murray / Jamie Murray |  GBR | 0 | 6 (6) | 6 (14) |
Thomaz Bellucci / André Sá| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Thomaz Bellucci | ||||
| – | André Sá | ||||
| Team Totals | |||||
Andy Murray / Jamie Murray| Pos | Seed | Competitor | |||
|---|---|---|---|---|---|
| – | Andy Murray | ||||
| – | Jamie Murray | ||||
| Team Totals | |||||
