| Date | 8 August 2016 — 11:05 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Nico Helwerth |  GER |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| – | Mónica Puig |  PUR | 2 | 6 | 6 | |
| 14 | Anastasiya Pavlyuchenkova |  RUS | 0 | 3 | 2 |
| Mónica Puig | Anastasiya Pavlyuchenkova | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 3 |
| Set #2 | 6 | 2 |
