| Date | 6 August 2016 — 13:55 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Tamara Vrhovec-Wójcik |  CRO |
| Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|
| Heather Watson |  GBR | 2 | 6 | 6 (5) | 6 | |
| Peng Shuai |  CHN | 1 | 4 | 7 (7) | 3 |
| Heather Watson | Peng Shuai | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 6 | 4 |
| Set #2 | 6 (5) | 7 (7) |
| Set #3 | 6 | 3 |
