| Date | 6 August 2016 — 13:55 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Tamara Vrhovec-Wójcik |  CRO |
| Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|
| Heather Watson |  GBR | 2 | 2 | 6 | 6 | 6 | |
| Peng Shuai |  CHN | 1 | 1 | 4 | 7 | 3 |
| Heather Watson | Peng Shuai | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 6 | 4 |
| Set 2 | 6 | 7 |
| Set 3 | 6 | 3 |
| Tie-break 2 | 5 | 7 |
