| Date | 7 August 2016 — 14:17 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Thomas Sweeney |  AUS |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 11 | Petra Kvitová |  CZE | 2 | 6 | 6 | |
| – | Tímea Babos |  HUN | 0 | 1 | 2 |
| Petra Kvitová | Tímea Babos | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 1 |
| Set #2 | 6 | 2 |
