| Date | 7 August 2016 — 18:50 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Paula Vieira |  BRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 3 | Garbiñe Muguruza |  ESP | 2 | 6 | 6 | |
| – | Andreea Mitu |  ROU | 0 | 2 | 2 |
| Garbiñe Muguruza | Andreea Mitu | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 2 |
| Set #2 | 6 | 2 |
